Copper particles generated during in situ laser-induced synthesis exhibit catalytic activity towards formation of gas phase

Dmitrii Gordeychuk, Vladimir Kochemirovsky, Victor Sorokoumov, Ilya Tumkin, Alexey Kuzmin, Irina Balova

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)

Abstract

The method of laser-induced chemical deposition of metal from solution was applied in the continuous in situ laser generation of metal copper catalysts for model organic synthesis reactions. The gas phase products producing during laser-induced copper deposition were analyzed by gas mass spectroscopy whereas solutions used for the copper deposition were investigated before and after laser irradiation using chromato-mass and NMR spectroscopy. It was found out that the catalysis of the studied organic reactions by metal catalysts generated during laser deposition process occurs only upon laser irradiation of the reaction mixture, in turn, the copper structures deposited under laser light exhibit no catalytic activity.

Original languageEnglish
Pages (from-to)57-61
Number of pages5
JournalJournal of Laser Micro Nanoengineering
Volume12
Issue number2
DOIs
StatePublished - 2017

Keywords

  • Catalysis
  • Copper
  • Gas mass spectroscopy
  • Laser-induced metal deposition

Scopus subject areas

  • Instrumentation
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

Cite this

@article{f4d18398049447f48f457e0639b5ee88,
title = "Copper particles generated during in situ laser-induced synthesis exhibit catalytic activity towards formation of gas phase",
abstract = "The method of laser-induced chemical deposition of metal from solution was applied in the continuous in situ laser generation of metal copper catalysts for model organic synthesis reactions. The gas phase products producing during laser-induced copper deposition were analyzed by gas mass spectroscopy whereas solutions used for the copper deposition were investigated before and after laser irradiation using chromato-mass and NMR spectroscopy. It was found out that the catalysis of the studied organic reactions by metal catalysts generated during laser deposition process occurs only upon laser irradiation of the reaction mixture, in turn, the copper structures deposited under laser light exhibit no catalytic activity.",
keywords = "Catalysis, Copper, Gas mass spectroscopy, Laser-induced metal deposition",
author = "Dmitrii Gordeychuk and Vladimir Kochemirovsky and Victor Sorokoumov and Ilya Tumkin and Alexey Kuzmin and Irina Balova",
year = "2017",
doi = "10.2961/jlmn.2017.02.0001",
language = "English",
volume = "12",
pages = "57--61",
journal = "Journal of Laser Micro Nanoengineering",
issn = "1880-0688",
publisher = "Japan Laser Processing",
number = "2",

}

Copper particles generated during in situ laser-induced synthesis exhibit catalytic activity towards formation of gas phase. / Gordeychuk, Dmitrii; Kochemirovsky, Vladimir; Sorokoumov, Victor; Tumkin, Ilya; Kuzmin, Alexey; Balova, Irina.

In: Journal of Laser Micro Nanoengineering, Vol. 12, No. 2, 2017, p. 57-61.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Copper particles generated during in situ laser-induced synthesis exhibit catalytic activity towards formation of gas phase

AU - Gordeychuk, Dmitrii

AU - Kochemirovsky, Vladimir

AU - Sorokoumov, Victor

AU - Tumkin, Ilya

AU - Kuzmin, Alexey

AU - Balova, Irina

PY - 2017

Y1 - 2017

N2 - The method of laser-induced chemical deposition of metal from solution was applied in the continuous in situ laser generation of metal copper catalysts for model organic synthesis reactions. The gas phase products producing during laser-induced copper deposition were analyzed by gas mass spectroscopy whereas solutions used for the copper deposition were investigated before and after laser irradiation using chromato-mass and NMR spectroscopy. It was found out that the catalysis of the studied organic reactions by metal catalysts generated during laser deposition process occurs only upon laser irradiation of the reaction mixture, in turn, the copper structures deposited under laser light exhibit no catalytic activity.

AB - The method of laser-induced chemical deposition of metal from solution was applied in the continuous in situ laser generation of metal copper catalysts for model organic synthesis reactions. The gas phase products producing during laser-induced copper deposition were analyzed by gas mass spectroscopy whereas solutions used for the copper deposition were investigated before and after laser irradiation using chromato-mass and NMR spectroscopy. It was found out that the catalysis of the studied organic reactions by metal catalysts generated during laser deposition process occurs only upon laser irradiation of the reaction mixture, in turn, the copper structures deposited under laser light exhibit no catalytic activity.

KW - Catalysis

KW - Copper

KW - Gas mass spectroscopy

KW - Laser-induced metal deposition

UR - http://www.scopus.com/inward/record.url?scp=85029548097&partnerID=8YFLogxK

U2 - 10.2961/jlmn.2017.02.0001

DO - 10.2961/jlmn.2017.02.0001

M3 - Article

VL - 12

SP - 57

EP - 61

JO - Journal of Laser Micro Nanoengineering

JF - Journal of Laser Micro Nanoengineering

SN - 1880-0688

IS - 2

ER -