Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods

Marina G. Shelyapina, Ekaterina A. Krylova, Yurii M. Zhukov, Irina A. Zvereva, Inocente Rodriguez-Iznaga, Vitalii Petranovskii, Sergio Fuentes-Moyado

Research output

Abstract

This article presents the results of a comprehensive study of copper-exchanged mordenite samples prepared from its ammonia and protonated forms (Si/Al = 10) using two different ion exchange methods: conventional and microwave (MW)-assisted. The protonated H-MOR-10 sample was obtained by calcination of commercial NH4-MOR-10; in this case, a slight degradation of the mordenite framework was observed, but the resulting defects were partially restored after the first ion-exchange procedure of protons for copper ions. The level of copper exchange in the studied materials was found to be limited to 70%. Regardless of the exchange procedure, the replacement of ammonium or proton ions with copper led to a linear increase in the a/b ratio of cell parameters in accordance with an increase in the level of copper exchange, which means that all Cu2+ cations are ion-exchangeable and enter the main mordenite channel. Thermal analysis indicated a correlation between the replacement of various ammonium and hydroxyl groups by copper ions during the exchange treatment and their dehydroxylation energy during thermal decomposition. As a conclusion: MW-assisted treatment proved itself as an efficacious method for the synthesis of copper-exchanged mordenites, which not only significantly reduces preparation time but leads to a systematically higher copper exchange leve
Original languageEnglish
Article number4216
Number of pages15
JournalMolecules
Volume24
Issue number23
Early online date20 Nov 2019
DOIs
Publication statusPublished - Dec 2019

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Microwaves
Ammonia
Copper
ammonia
microwaves
copper
Ion Exchange
Ions
ions
Ammonium Compounds
Protons
Ion exchange
Hot Temperature
protons
mordenite
Hydroxyl Radical
Calcination
roasting
Thermoanalysis
thermal decomposition

Cite this

@article{b723c9cc78424cf597ce0f627d9d7f1e,
title = "Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods",
abstract = "This article presents the results of a comprehensive study of copper-exchanged mordenite samples prepared from its ammonia and protonated forms (Si/Al = 10) using two different ion exchange methods: conventional and microwave (MW)-assisted. The protonated H-MOR-10 sample was obtained by calcination of commercial NH4-MOR-10; in this case, a slight degradation of the mordenite framework was observed, but the resulting defects were partially restored after the first ion-exchange procedure of protons for copper ions. The level of copper exchange in the studied materials was found to be limited to 70{\%}. Regardless of the exchange procedure, the replacement of ammonium or proton ions with copper led to a linear increase in the a/b ratio of cell parameters in accordance with an increase in the level of copper exchange, which means that all Cu2+ cations are ion-exchangeable and enter the main mordenite channel. Thermal analysis indicated a correlation between the replacement of various ammonium and hydroxyl groups by copper ions during the exchange treatment and their dehydroxylation energy during thermal decomposition. As a conclusion: MW-assisted treatment proved itself as an efficacious method for the synthesis of copper-exchanged mordenites, which not only significantly reduces preparation time but leads to a systematically higher copper exchange leve",
keywords = "морденит, микроволновой ионообмен, ЯМР, ТГА, РФЭС, Mordenite, microwave-assisted ion exchange, XRD, ICP-OES, NMR, TGA, XPS",
author = "Shelyapina, {Marina G.} and Krylova, {Ekaterina A.} and Zhukov, {Yurii M.} and Zvereva, {Irina A.} and Inocente Rodriguez-Iznaga and Vitalii Petranovskii and Sergio Fuentes-Moyado",
note = "Shelyapina, M.G.; Krylova, E.A.; Zhukov, Y.M.; Zvereva, I.A.; Rodriguez-Iznaga, I.; Petranovskii, V.; Fuentes-Moyado, S. Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods. Molecules 2019, 24, 4216.",
year = "2019",
month = "12",
doi = "10.3390/molecules24234216",
language = "English",
volume = "24",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "23",

}

Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods. / Shelyapina, Marina G.; Krylova, Ekaterina A.; Zhukov, Yurii M.; Zvereva, Irina A.; Rodriguez-Iznaga, Inocente; Petranovskii, Vitalii; Fuentes-Moyado, Sergio.

In: Molecules, Vol. 24, No. 23, 4216, 12.2019.

Research output

TY - JOUR

T1 - Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods

AU - Shelyapina, Marina G.

AU - Krylova, Ekaterina A.

AU - Zhukov, Yurii M.

AU - Zvereva, Irina A.

AU - Rodriguez-Iznaga, Inocente

AU - Petranovskii, Vitalii

AU - Fuentes-Moyado, Sergio

N1 - Shelyapina, M.G.; Krylova, E.A.; Zhukov, Y.M.; Zvereva, I.A.; Rodriguez-Iznaga, I.; Petranovskii, V.; Fuentes-Moyado, S. Comprehensive Analysis of the Copper Exchange Implemented in Ammonia and Protonated Forms of Mordenite Using Microwave and Conventional Methods. Molecules 2019, 24, 4216.

PY - 2019/12

Y1 - 2019/12

N2 - This article presents the results of a comprehensive study of copper-exchanged mordenite samples prepared from its ammonia and protonated forms (Si/Al = 10) using two different ion exchange methods: conventional and microwave (MW)-assisted. The protonated H-MOR-10 sample was obtained by calcination of commercial NH4-MOR-10; in this case, a slight degradation of the mordenite framework was observed, but the resulting defects were partially restored after the first ion-exchange procedure of protons for copper ions. The level of copper exchange in the studied materials was found to be limited to 70%. Regardless of the exchange procedure, the replacement of ammonium or proton ions with copper led to a linear increase in the a/b ratio of cell parameters in accordance with an increase in the level of copper exchange, which means that all Cu2+ cations are ion-exchangeable and enter the main mordenite channel. Thermal analysis indicated a correlation between the replacement of various ammonium and hydroxyl groups by copper ions during the exchange treatment and their dehydroxylation energy during thermal decomposition. As a conclusion: MW-assisted treatment proved itself as an efficacious method for the synthesis of copper-exchanged mordenites, which not only significantly reduces preparation time but leads to a systematically higher copper exchange leve

AB - This article presents the results of a comprehensive study of copper-exchanged mordenite samples prepared from its ammonia and protonated forms (Si/Al = 10) using two different ion exchange methods: conventional and microwave (MW)-assisted. The protonated H-MOR-10 sample was obtained by calcination of commercial NH4-MOR-10; in this case, a slight degradation of the mordenite framework was observed, but the resulting defects were partially restored after the first ion-exchange procedure of protons for copper ions. The level of copper exchange in the studied materials was found to be limited to 70%. Regardless of the exchange procedure, the replacement of ammonium or proton ions with copper led to a linear increase in the a/b ratio of cell parameters in accordance with an increase in the level of copper exchange, which means that all Cu2+ cations are ion-exchangeable and enter the main mordenite channel. Thermal analysis indicated a correlation between the replacement of various ammonium and hydroxyl groups by copper ions during the exchange treatment and their dehydroxylation energy during thermal decomposition. As a conclusion: MW-assisted treatment proved itself as an efficacious method for the synthesis of copper-exchanged mordenites, which not only significantly reduces preparation time but leads to a systematically higher copper exchange leve

KW - морденит

KW - микроволновой ионообмен

KW - ЯМР

KW - ТГА

KW - РФЭС

KW - Mordenite

KW - microwave-assisted ion exchange

KW - XRD

KW - ICP-OES

KW - NMR

KW - TGA

KW - XPS

UR - https://www.mdpi.com/1420-3049/24/23

U2 - 10.3390/molecules24234216

DO - 10.3390/molecules24234216

M3 - Article

VL - 24

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 23

M1 - 4216

ER -