Complex Amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)

A. M. Chernysheva, P. A. Shelyganov, I. V. Kazakov, A. Y. Timoshkin

Research output

3 Citations (Scopus)

Abstract

Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.
Original languageEnglish
Pages (from-to)665-669
JournalRussian Journal of General Chemistry
Volume87
Issue number4
DOIs
Publication statusPublished - 2017

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Alkali Metals
Reaction products
Nuclear magnetic resonance spectroscopy
Infrared spectroscopy
Thermodynamics
X rays
aluminum chloride
gallium chloride

Cite this

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title = "Complex Amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)",
abstract = "Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.",
keywords = "amidoboranes, complex amidoboranes, quantum-chemical calculations, NMR",
author = "Chernysheva, {A. M.} and Shelyganov, {P. A.} and Kazakov, {I. V.} and Timoshkin, {A. Y.}",
year = "2017",
doi = "10.1134/S1070363217040016",
language = "English",
volume = "87",
pages = "665--669",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

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TY - JOUR

T1 - Complex Amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)

AU - Chernysheva, A. M.

AU - Shelyganov, P. A.

AU - Kazakov, I. V.

AU - Timoshkin, A. Y.

PY - 2017

Y1 - 2017

N2 - Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.

AB - Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.

KW - amidoboranes

KW - complex amidoboranes

KW - quantum-chemical calculations

KW - NMR

U2 - 10.1134/S1070363217040016

DO - 10.1134/S1070363217040016

M3 - Article

VL - 87

SP - 665

EP - 669

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -