Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents

A. Yu Bilibin, T. M. Shcherbinina, N. V. Girbasova, V. T. Lebedev, Yu V. Kulvelis, V. S. Molchanov, I. M. Zorin

Research output

3 Citations (Scopus)

Abstract

Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTAAMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water–dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water–dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mix
Original languageUndefined
JournalDesigned Monomers and Polymers
DOIs
Publication statusPublished - 2016
Externally publishedYes

Cite this

@article{fd3e46129a324971b1c306d34fdd11d2,
title = "Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents",
abstract = "Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTAAMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water–dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water–dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5{\%}) the surfmers form reverse micelles in the mix",
keywords = "Micelle formation, polymerizable surfactants, counterion, micelles, solvents, polarity",
author = "Bilibin, {A. Yu} and Shcherbinina, {T. M.} and Girbasova, {N. V.} and Lebedev, {V. T.} and Kulvelis, {Yu V.} and Molchanov, {V. S.} and Zorin, {I. M.}",
year = "2016",
doi = "10.1080/15685551.2016.1169371",
language = "не определен",
journal = "Designed Monomers and Polymers",
issn = "1385-772X",
publisher = "Taylor & Francis",

}

TY - JOUR

T1 - Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents

AU - Bilibin, A. Yu

AU - Shcherbinina, T. M.

AU - Girbasova, N. V.

AU - Lebedev, V. T.

AU - Kulvelis, Yu V.

AU - Molchanov, V. S.

AU - Zorin, I. M.

PY - 2016

Y1 - 2016

N2 - Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTAAMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water–dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water–dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mix

AB - Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTAAMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water–dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water–dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mix

KW - Micelle formation

KW - polymerizable surfactants

KW - counterion

KW - micelles

KW - solvents

KW - polarity

U2 - 10.1080/15685551.2016.1169371

DO - 10.1080/15685551.2016.1169371

M3 - статья

JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

SN - 1385-772X

ER -