Research output: Contribution to journal › Article › peer-review
Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides. / Anisimova, T.B.; Kashina, M.V.; Kinzhalov, M.A.; Guedes Da Silva, M.F.C.; Pombeiro, A.J.L.; Luzyanin, K.V.
In: Mendeleev Communications, Vol. 36, No. 2, 01.03.2026, p. 135-137.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides
AU - Anisimova, T.B.
AU - Kashina, M.V.
AU - Kinzhalov, M.A.
AU - Guedes Da Silva, M.F.C.
AU - Pombeiro, A.J.L.
AU - Luzyanin, K.V.
N1 - Export Date: 23 February 2026; Cited By: 0; Correspondence Address: M.A. Kinzhalov; Institute of Chemistry, St. Petersburg State University, St. Petersburg, 198504, Russian Federation; email: m.kinzhalov@spbu.ru; K.V. Luzyanin; Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, United Kingdom; email: konstantin.luzyanin@liverpool.ac.uk; CODEN: MENCE
PY - 2026/3/1
Y1 - 2026/3/1
N2 - The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91% yields with full retention of configuration at stereogenic centers. Structural analysis of the representative Pdii complexes revealed isostructural enantiomeric pairs with slightly distorted square-planar geometry, featuring labile Pd–Cl bonds trans to the ADC ligand. © 2026 Mendeleev Communications.
AB - The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91% yields with full retention of configuration at stereogenic centers. Structural analysis of the representative Pdii complexes revealed isostructural enantiomeric pairs with slightly distorted square-planar geometry, featuring labile Pd–Cl bonds trans to the ADC ligand. © 2026 Mendeleev Communications.
KW - amino acid amides
KW - aminocarbene complexes
KW - chiral complexes
KW - gold complexes
KW - isocyanide complexes
KW - palladium complexes
KW - platinum complexes
UR - https://www.mendeley.com/catalogue/7e6d2ceb-5543-3c76-af6e-b79871e373df/
U2 - 10.71267/mencom.7888
DO - 10.71267/mencom.7888
M3 - статья
VL - 36
SP - 135
EP - 137
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 2
ER -
ID: 149216245