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Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides. / Anisimova, T.B.; Kashina, M.V.; Kinzhalov, M.A.; Guedes Da Silva, M.F.C.; Pombeiro, A.J.L.; Luzyanin, K.V.

In: Mendeleev Communications, Vol. 36, No. 2, 01.03.2026, p. 135-137.

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Anisimova, T.B. ; Kashina, M.V. ; Kinzhalov, M.A. ; Guedes Da Silva, M.F.C. ; Pombeiro, A.J.L. ; Luzyanin, K.V. / Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides. In: Mendeleev Communications. 2026 ; Vol. 36, No. 2. pp. 135-137.

BibTeX

@article{9f9ee2ff6d5349d48f69bce5ce4d332d,
title = "Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides",
abstract = "The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91% yields with full retention of configuration at stereogenic centers. Structural analysis of the representative Pdii complexes revealed isostructural enantiomeric pairs with slightly distorted square-planar geometry, featuring labile Pd–Cl bonds trans to the ADC ligand. {\textcopyright} 2026 Mendeleev Communications.",
keywords = "amino acid amides, aminocarbene complexes, chiral complexes, gold complexes, isocyanide complexes, palladium complexes, platinum complexes",
author = "T.B. Anisimova and M.V. Kashina and M.A. Kinzhalov and {Guedes Da Silva}, M.F.C. and A.J.L. Pombeiro and K.V. Luzyanin",
note = "Export Date: 23 February 2026; Cited By: 0; Correspondence Address: M.A. Kinzhalov; Institute of Chemistry, St. Petersburg State University, St. Petersburg, 198504, Russian Federation; email: m.kinzhalov@spbu.ru; K.V. Luzyanin; Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, United Kingdom; email: konstantin.luzyanin@liverpool.ac.uk; CODEN: MENCE",
year = "2026",
month = mar,
day = "1",
doi = "10.71267/mencom.7888",
language = "Английский",
volume = "36",
pages = "135--137",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "2",

}

RIS

TY - JOUR

T1 - Chiral acyclic diaminocarbene complexes of palladium(ii), platinum(ii) and gold(i) from metal-mediated coupling of isocyanides with chiral amino acid amides

AU - Anisimova, T.B.

AU - Kashina, M.V.

AU - Kinzhalov, M.A.

AU - Guedes Da Silva, M.F.C.

AU - Pombeiro, A.J.L.

AU - Luzyanin, K.V.

N1 - Export Date: 23 February 2026; Cited By: 0; Correspondence Address: M.A. Kinzhalov; Institute of Chemistry, St. Petersburg State University, St. Petersburg, 198504, Russian Federation; email: m.kinzhalov@spbu.ru; K.V. Luzyanin; Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, United Kingdom; email: konstantin.luzyanin@liverpool.ac.uk; CODEN: MENCE

PY - 2026/3/1

Y1 - 2026/3/1

N2 - The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91% yields with full retention of configuration at stereogenic centers. Structural analysis of the representative Pdii complexes revealed isostructural enantiomeric pairs with slightly distorted square-planar geometry, featuring labile Pd–Cl bonds trans to the ADC ligand. © 2026 Mendeleev Communications.

AB - The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91% yields with full retention of configuration at stereogenic centers. Structural analysis of the representative Pdii complexes revealed isostructural enantiomeric pairs with slightly distorted square-planar geometry, featuring labile Pd–Cl bonds trans to the ADC ligand. © 2026 Mendeleev Communications.

KW - amino acid amides

KW - aminocarbene complexes

KW - chiral complexes

KW - gold complexes

KW - isocyanide complexes

KW - palladium complexes

KW - platinum complexes

UR - https://www.mendeley.com/catalogue/7e6d2ceb-5543-3c76-af6e-b79871e373df/

U2 - 10.71267/mencom.7888

DO - 10.71267/mencom.7888

M3 - статья

VL - 36

SP - 135

EP - 137

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 2

ER -

ID: 149216245