Chiral Acyclic Diaminocarbene Complexes of Palladium (II) Immobilized on a Polymeric Support As Promising Catalysts of the Suzuki Reaction. / Mikhailov, V. N.; Korvinson, K.; Sorokoumov, V. N.
In: Russian Journal of General Chemistry, Vol. 86, No. 11, 2016, p. 2473-2476.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Chiral Acyclic Diaminocarbene Complexes of Palladium (II) Immobilized on a Polymeric Support As Promising Catalysts of the Suzuki Reaction
AU - Mikhailov, V. N.
AU - Korvinson, K.
AU - Sorokoumov, V. N.
PY - 2016
Y1 - 2016
N2 - Metal-promoted nucleophilic addition of primary amino group of a natural L-amino acid anchored on polystyrene support to coordinated isonitrile substrate has afforded preparation and simultaneous immo- bilization of chiral acyclic diaminocarbene complex of palladium(II). The obtained catalytic system is stable under conditions of the Suzuki reaction and demonstrates good catalytic activity in the reaction with a sterically hindered substrate.
AB - Metal-promoted nucleophilic addition of primary amino group of a natural L-amino acid anchored on polystyrene support to coordinated isonitrile substrate has afforded preparation and simultaneous immo- bilization of chiral acyclic diaminocarbene complex of palladium(II). The obtained catalytic system is stable under conditions of the Suzuki reaction and demonstrates good catalytic activity in the reaction with a sterically hindered substrate.
KW - catalysis
KW - palladium
KW - diaminocarbene
KW - chiral catalyst
KW - Suzuki reaction
U2 - 10.1134/S1070363216110128
DO - 10.1134/S1070363216110128
M3 - статья
VL - 86
SP - 2473
EP - 2476
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 11
ER -
ID: 7629491