Research output: Contribution to journal › Article › peer-review
Carbonylation of Aryl Halides Catalyzed by Modified Cobalt Carbonyls. / Zhesko, T. E.; Boyarskii, V. P.
In: Russian Journal of General Chemistry, Vol. 68, No. 1, 01.1998, p. 78-82.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Carbonylation of Aryl Halides Catalyzed by Modified Cobalt Carbonyls
AU - Zhesko, T. E.
AU - Boyarskii, V. P.
PY - 1998/1
Y1 - 1998/1
N2 - The effect of the substrate structure and the catalytic system on the rate of carbonylation of aryl halides in the presence of modified cobalt carbonyls was studied. Electron-acceptor substituents in the aryl halides favor faster carbonylation. The reaction mechanism was examined, and evidence was obtained for aryl halide activation by the SRN1 mechanism. The activity order of cocatalysts is considered, and new catalytic systems were proposed.
AB - The effect of the substrate structure and the catalytic system on the rate of carbonylation of aryl halides in the presence of modified cobalt carbonyls was studied. Electron-acceptor substituents in the aryl halides favor faster carbonylation. The reaction mechanism was examined, and evidence was obtained for aryl halide activation by the SRN1 mechanism. The activity order of cocatalysts is considered, and new catalytic systems were proposed.
UR - http://www.scopus.com/inward/record.url?scp=0032398771&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0032398771
VL - 68
SP - 78
EP - 82
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 1
ER -
ID: 87469465