Calculation of the equilibrium constants and binding cooperativity parameters of ammonia with Group II metal cations in solution

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Abstract

The matrix model was used to analyze the distribution diagrams and formation functions of ammonia complexes [M(NH3) n ] 2+ (n = 0-4) of Group II metal ions (Mg2+, Ca 2+, Zn2+, Cd2+, and Hg2+) in solution. Intrinsic binding constants of the ligand (K in) and mutual influence corrections (ω) for complex formation with aqua ions in solution were calculated. The equilibrium constants were calculated by the matrix method. The coordination sphere of Mg2+, Ca2+, and Zn2+ by ammonia in a cooperative manner; with Cd2+ and Hg2+, both cooperative and anticooperative binding occur concurrently. Possibilities for differentiation between tetrahedral and square planar coordination polyhedra on the basis of the characteristic features of ligand binding, determined by the matrix model, are discussed.

Original languageEnglish
Pages (from-to)2087-2095
Number of pages9
JournalRussian Journal of General Chemistry
Volume79
Issue number10
DOIs
Publication statusPublished - 1 Oct 2009

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Scopus subject areas

  • Chemistry(all)

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