Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds

M. Colmont, D. Endara, M. Huvé, S. V. Krivovichev, O. Mentré

Research output

2 Citations (Scopus)

Abstract

In the Bi 2O 3-MO-P 2O 5 diagram, on the basis of previous compounds based on 2D-ribbon like units, we have predicted and prepared the infinite term. It contains [Bi 2O 2] 2+ planes arranged within a never-observed crystallographic form. In this series, the ribbons-like units are polycations built on the linkage of n O(Bi,M) 4 tetrahedra along their width and infinite in a perpendicular dimension. Hence, this novel form completes the continuous series of analogue compounds, whose building units now extend from the single chain to the infinite plane, via a number of discrete n values (2,3,4,5,6,7,8,9,10,11). The presented materials of formulae Bi 4MP 2O 12 (M= Zn and Mg) roughly show the same crystal structure. However different arrangements of the groups located between the [Bi 2O 2] 2+ planes are at the origin of a complex superstructure in the case of the zinc compounds.

Original languageEnglish
Title of host publicationSolid-State Chemistry of Inorganic Materials VIII
Pages15-20
Number of pages6
Volume1309
DOIs
Publication statusPublished - 1 Dec 2011
Event2010 MRS Fall Meeting - Boston, MA
Duration: 29 Nov 20103 Dec 2010

Conference

Conference2010 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period29/11/103/12/10

Fingerprint

Zinc Compounds
Zinc compounds
ribbons
Crystal structure
zinc compounds
linkages
tetrahedrons
diagrams
analogs
crystal structure
polycations

Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Colmont, M., Endara, D., Huvé, M., Krivovichev, S. V., & Mentré, O. (2011). Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds. In Solid-State Chemistry of Inorganic Materials VIII (Vol. 1309, pp. 15-20) https://doi.org/10.1557/opl.2011.98
Colmont, M. ; Endara, D. ; Huvé, M. ; Krivovichev, S. V. ; Mentré, O. / Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds. Solid-State Chemistry of Inorganic Materials VIII. Vol. 1309 2011. pp. 15-20
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Colmont, M, Endara, D, Huvé, M, Krivovichev, SV & Mentré, O 2011, Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds. in Solid-State Chemistry of Inorganic Materials VIII. vol. 1309, pp. 15-20, Boston, MA, 29/11/10. https://doi.org/10.1557/opl.2011.98

Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds. / Colmont, M.; Endara, D.; Huvé, M.; Krivovichev, S. V.; Mentré, O.

Solid-State Chemistry of Inorganic Materials VIII. Vol. 1309 2011. p. 15-20.

Research output

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Colmont M, Endara D, Huvé M, Krivovichev SV, Mentré O. Building 3D materials from adjustable 2D-units; towards the design of new Bi-based compounds. In Solid-State Chemistry of Inorganic Materials VIII. Vol. 1309. 2011. p. 15-20 https://doi.org/10.1557/opl.2011.98