Binuclear and polymeric bromobismuthate complexes

Crystal structures and thermal stability

Sergey A. Adonin, Igor D. Gorokh, Denis G. Samsonenko, Alexander S. Novikov, Ilya V. Korolkov, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Research outputpeer-review

1 Citation (Scopus)

Abstract

A series of nine bromobismuthate complexes containing Py-derived cations – (cat)3[Bi2Br9] (cat = 1-i-PrPy (1), 3,5-MePyH (2), 1,2-MePy (3), 1,3-MePy (4), 1-Et-3-MePy (5), 1-Et-4-MePy (6), 1,2,4,6-MePy (7)), (2-MePyH){[BiBr4]} (8) and (1-Bz-4-MePy)4[Bi2Br10] (9) were prepared and characterized by X-ray diffractometry. Thermal stability was studied for synthesized compounds, as well as for the related complexes reported earlier.

Original languageEnglish
Pages (from-to)318-322
Number of pages5
JournalPolyhedron
Volume159
DOIs
Publication statusPublished - 1 Feb 2019

Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Adonin, S. A., Gorokh, I. D., Samsonenko, D. G., Novikov, A. S., Korolkov, I. V., Plyusnin, P. E., ... Fedin, V. P. (2019). Binuclear and polymeric bromobismuthate complexes: Crystal structures and thermal stability. Polyhedron, 159, 318-322. https://doi.org/10.1016/j.poly.2018.12.017
Adonin, Sergey A. ; Gorokh, Igor D. ; Samsonenko, Denis G. ; Novikov, Alexander S. ; Korolkov, Ilya V. ; Plyusnin, Pavel E. ; Sokolov, Maxim N. ; Fedin, Vladimir P. / Binuclear and polymeric bromobismuthate complexes : Crystal structures and thermal stability. In: Polyhedron. 2019 ; Vol. 159. pp. 318-322.
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abstract = "A series of nine bromobismuthate complexes containing Py-derived cations – (cat)3[Bi2Br9] (cat = 1-i-PrPy (1), 3,5-MePyH (2), 1,2-MePy (3), 1,3-MePy (4), 1-Et-3-MePy (5), 1-Et-4-MePy (6), 1,2,4,6-MePy (7)), (2-MePyH){[BiBr4]} (8) and (1-Bz-4-MePy)4[Bi2Br10] (9) were prepared and characterized by X-ray diffractometry. Thermal stability was studied for synthesized compounds, as well as for the related complexes reported earlier.",
keywords = "Bismuth, Crystal structure, Halide complexes, Halometalate, Hirshfeld surface analysis",
author = "Adonin, {Sergey A.} and Gorokh, {Igor D.} and Samsonenko, {Denis G.} and Novikov, {Alexander S.} and Korolkov, {Ilya V.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
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Adonin, SA, Gorokh, ID, Samsonenko, DG, Novikov, AS, Korolkov, IV, Plyusnin, PE, Sokolov, MN & Fedin, VP 2019, 'Binuclear and polymeric bromobismuthate complexes: Crystal structures and thermal stability', Polyhedron, vol. 159, pp. 318-322. https://doi.org/10.1016/j.poly.2018.12.017

Binuclear and polymeric bromobismuthate complexes : Crystal structures and thermal stability. / Adonin, Sergey A.; Gorokh, Igor D.; Samsonenko, Denis G.; Novikov, Alexander S.; Korolkov, Ilya V.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.

In: Polyhedron, Vol. 159, 01.02.2019, p. 318-322.

Research outputpeer-review

TY - JOUR

T1 - Binuclear and polymeric bromobismuthate complexes

T2 - Crystal structures and thermal stability

AU - Adonin, Sergey A.

AU - Gorokh, Igor D.

AU - Samsonenko, Denis G.

AU - Novikov, Alexander S.

AU - Korolkov, Ilya V.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/2/1

Y1 - 2019/2/1

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AB - A series of nine bromobismuthate complexes containing Py-derived cations – (cat)3[Bi2Br9] (cat = 1-i-PrPy (1), 3,5-MePyH (2), 1,2-MePy (3), 1,3-MePy (4), 1-Et-3-MePy (5), 1-Et-4-MePy (6), 1,2,4,6-MePy (7)), (2-MePyH){[BiBr4]} (8) and (1-Bz-4-MePy)4[Bi2Br10] (9) were prepared and characterized by X-ray diffractometry. Thermal stability was studied for synthesized compounds, as well as for the related complexes reported earlier.

KW - Bismuth

KW - Crystal structure

KW - Halide complexes

KW - Halometalate

KW - Hirshfeld surface analysis

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DO - 10.1016/j.poly.2018.12.017

M3 - Article

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SP - 318

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JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

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