Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks

Sergey A. Adonin, Mikhail A. Bondarenko, Alexander S. Novikov, Pavel A. Abramov, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Research output

Abstract

Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.

Original languageEnglish
Pages (from-to)1141-1145
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume645
Issue number18-19
Early online date23 Sep 2019
DOIs
Publication statusPublished - Oct 2019

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Antimony
Bromides
Cations
Thermodynamic stability

Scopus subject areas

  • Inorganic Chemistry

Cite this

Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Novikov, Alexander S. ; Abramov, Pavel A. ; Plyusnin, Pavel E. ; Sokolov, Maxim N. ; Fedin, Vladimir P. / Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations : Substituent-dependent Assembly of Polymeric Frameworks. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2019 ; Vol. 645, No. 18-19. pp. 1141-1145.
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abstract = "Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.",
keywords = "Antimony, Halide complex, Halogen bonding, Polyhalogens, Supramolecular interactions",
author = "Adonin, {Sergey A.} and Bondarenko, {Mikhail A.} and Novikov, {Alexander S.} and Abramov, {Pavel A.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
year = "2019",
month = "10",
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Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations : Substituent-dependent Assembly of Polymeric Frameworks. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Abramov, Pavel A.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 645, No. 18-19, 10.2019, p. 1141-1145.

Research output

TY - JOUR

T1 - Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations

T2 - Substituent-dependent Assembly of Polymeric Frameworks

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/10

Y1 - 2019/10

N2 - Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.

AB - Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.

KW - Antimony

KW - Halide complex

KW - Halogen bonding

KW - Polyhalogens

KW - Supramolecular interactions

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U2 - 10.1002/zaac.201900165

DO - 10.1002/zaac.201900165

M3 - Article

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VL - 645

SP - 1141

EP - 1145

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 18-19

ER -