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An Isoxazole Strategy for Molybdenum-Mediated Synthesis of 5-Mono- and 4,5-Disubstituted 1 H-Pyrrole-2,3-diones. / Galenko, Ekaterina E.; Puzyk, Aleksandra M.; Novikov, Mikhail S.; Khlebnikov, Alexander F.

In: Journal of Organic Chemistry, Vol. 87, No. 9, 06.05.2022, p. 6459-6470.

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@article{f49e8a55de7b4d2280936473d30085e3,
title = "An Isoxazole Strategy for Molybdenum-Mediated Synthesis of 5-Mono- and 4,5-Disubstituted 1 H-Pyrrole-2,3-diones",
abstract = "The synthesis of 5-aryl- and 4-aryl/hetaryl/cyclopropyl/alkynyl-5-aryl-1H-pyrrole-2,3-diones by formal isomerization of isoxazole-5-carbaldehydes mediated Mo(CO)6 in wet MeCN has been developed. The resulting 1H-pyrrole-2,3-diones are good precursors for substituted 1H-pyrrolo[2,3-b]quinoxalines. ",
author = "Galenko, {Ekaterina E.} and Puzyk, {Aleksandra M.} and Novikov, {Mikhail S.} and Khlebnikov, {Alexander F.}",
note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society. All rights reserved.",
year = "2022",
month = may,
day = "6",
doi = "10.1021/acs.joc.2c00386",
language = "English",
volume = "87",
pages = "6459--6470",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "9",

}

RIS

TY - JOUR

T1 - An Isoxazole Strategy for Molybdenum-Mediated Synthesis of 5-Mono- and 4,5-Disubstituted 1 H-Pyrrole-2,3-diones

AU - Galenko, Ekaterina E.

AU - Puzyk, Aleksandra M.

AU - Novikov, Mikhail S.

AU - Khlebnikov, Alexander F.

N1 - Publisher Copyright: © 2022 American Chemical Society. All rights reserved.

PY - 2022/5/6

Y1 - 2022/5/6

N2 - The synthesis of 5-aryl- and 4-aryl/hetaryl/cyclopropyl/alkynyl-5-aryl-1H-pyrrole-2,3-diones by formal isomerization of isoxazole-5-carbaldehydes mediated Mo(CO)6 in wet MeCN has been developed. The resulting 1H-pyrrole-2,3-diones are good precursors for substituted 1H-pyrrolo[2,3-b]quinoxalines.

AB - The synthesis of 5-aryl- and 4-aryl/hetaryl/cyclopropyl/alkynyl-5-aryl-1H-pyrrole-2,3-diones by formal isomerization of isoxazole-5-carbaldehydes mediated Mo(CO)6 in wet MeCN has been developed. The resulting 1H-pyrrole-2,3-diones are good precursors for substituted 1H-pyrrolo[2,3-b]quinoxalines.

UR - http://www.scopus.com/inward/record.url?scp=85128685198&partnerID=8YFLogxK

U2 - 10.1021/acs.joc.2c00386

DO - 10.1021/acs.joc.2c00386

M3 - Article

AN - SCOPUS:85128685198

VL - 87

SP - 6459

EP - 6470

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 9

ER -

ID: 94983185