Abstract
The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.
| Original language | English |
|---|---|
| Title of host publication | Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature |
| Subtitle of host publication | Conference proceedings |
| Editors | Olga V. Frank-Kamenetskaya, Dmitry Yu. Vlasov, Elena G. Panova, Sofia N. Lessovaia |
| Place of Publication | Cham |
| Publisher | Springer |
| Pages | 695-719 |
| ISBN (Electronic) | 9783030216146 |
| ISBN (Print) | 9783030216139 |
| DOIs | |
| Publication status | E-pub ahead of print - 30 Aug 2019 |
| Event | VI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society - СПбГУ, Санкт-Петербург Duration: 24 Sep 2018 → 27 Sep 2018 Conference number: VI |
Publication series
| Name | Lecture Notes in Earth System Sciences |
|---|---|
| ISSN (Print) | 2193-8571 |
| ISSN (Electronic) | 2193-858X |
Conference
| Conference | VI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society |
|---|---|
| Country | Russian Federation |
| City | Санкт-Петербург |
| Period | 24/09/18 → 27/09/18 |
Fingerprint
Scopus subject areas
- Computers in Earth Sciences
- Earth and Planetary Sciences(all)
Cite this
}
Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. / Kotelnikova, Elena N.; Isakov, Anton I.; Kryuchkova, Lyudmila Yu.; Zolotarev, Andrey A.; Bocharov, Sergey N.; Lorenz, Heike.
Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. ed. / Olga V. Frank-Kamenetskaya; Dmitry Yu. Vlasov; Elena G. Panova; Sofia N. Lessovaia. Cham : Springer, 2020. p. 695-719 (Lecture Notes in Earth System Sciences).Research output › › peer-review
TY - CHAP
T1 - Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems
AU - Kotelnikova, Elena N.
AU - Isakov, Anton I.
AU - Kryuchkova, Lyudmila Yu.
AU - Zolotarev, Andrey A.
AU - Bocharov, Sergey N.
AU - Lorenz, Heike
PY - 2019/8/30
Y1 - 2019/8/30
N2 - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.
AB - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.
KW - Chiral molecules
KW - Non-equimolar compounds
KW - Organic acids
KW - Phase diagrams
KW - Racemates
KW - Solid solutions
UR - http://www.scopus.com/inward/record.url?scp=85072069430&partnerID=8YFLogxK
U2 - 10.1007/978-3-030-21614-6_37
DO - 10.1007/978-3-030-21614-6_37
M3 - Chapter
SN - 9783030216139
T3 - Lecture Notes in Earth System Sciences
SP - 695
EP - 719
BT - Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature
A2 - Frank-Kamenetskaya, Olga V.
A2 - Vlasov, Dmitry Yu.
A2 - Panova, Elena G.
A2 - Lessovaia, Sofia N.
PB - Springer
CY - Cham
ER -