Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems

Elena N. Kotelnikova, Anton I. Isakov, Lyudmila Yu. Kryuchkova, Andrey A. Zolotarev, Sergey N. Bocharov, Heike Lorenz

Research outputpeer-review

Abstract

The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.

Original languageEnglish
Title of host publicationProcesses and Phenomena on the Boundary Between Biogenic and Abiogenic Nature
Subtitle of host publicationConference proceedings
EditorsOlga V. Frank-Kamenetskaya, Dmitry Yu. Vlasov, Elena G. Panova, Sofia N. Lessovaia
Place of PublicationCham
PublisherSpringer Nature
Pages695-719
ISBN (Electronic)9783030216146
ISBN (Print)9783030216139
DOIs
Publication statusPublished - 2020
EventVI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society - СПбГУ, Санкт-Петербург
Duration: 24 Sep 201827 Sep 2018
Conference number: VI

Publication series

NameLecture Notes in Earth System Sciences
ISSN (Print)2193-8571
ISSN (Electronic)2193-858X

Conference

ConferenceVI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society
CountryRussian Federation
CityСанкт-Петербург
Period24/09/1827/09/18

Scopus subject areas

  • Computers in Earth Sciences
  • Earth and Planetary Sciences(all)

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  • Cite this

    Kotelnikova, E. N., Isakov, A. I., Kryuchkova, L. Y., Zolotarev, A. A., Bocharov, S. N., & Lorenz, H. (2020). Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. In O. V. Frank-Kamenetskaya, D. Y. Vlasov, E. G. Panova, & S. N. Lessovaia (Eds.), Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings (pp. 695-719). (Lecture Notes in Earth System Sciences). Springer Nature. https://doi.org/10.1007/978-3-030-21614-6_37