A 13C solid-state NMR study of cryptophane-E:chloromethane inclusion complexes

Zdeněk Tošner, Oleg Petrov, Sergey V. Dvinskikh, Jozef Kowalewski, Dick Sandström

Research output: Contribution to journalArticlepeer-review

20 Scopus citations


In this Letter, we demonstrate the use of separated local-field NMR spectroscopy under magic-angle spinning conditions as a means of studying molecular reorientation in solid inclusion compounds. Site-resolved 1H-13C dipolar couplings were estimated in complexes between cryptophane-E and chloromethanes. We show that the mobilities of encaged guests in the solid state and of guests inside the host cavity in the isotropic liquid solution are very similar.

Original languageEnglish
Pages (from-to)208-211
Number of pages4
JournalChemical Physics Letters
Issue number1-3
StatePublished - 11 Apr 2004

Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry


Dive into the research topics of 'A <sup>13</sup>C solid-state NMR study of cryptophane-E:chloromethane inclusion complexes'. Together they form a unique fingerprint.

Cite this