A Solution-Solid Phase Equilibrium in Ternary Systems Containing d-Elements Salts and Mixed Oxygen-Donor Solvent

N.A. Bogachev, A.O. Gorbunov, M. Yu Skripkin, A.B. Nikol’skii

Research outputpeer-review

Abstract

The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

Original languageEnglish
Pages (from-to)1142-1153
JournalRussian Journal of General Chemistry
Volume89
Issue number6
DOIs
Publication statusPublished - 1 Jun 2019

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Ternary systems
Phase equilibria
Solid solutions
Salts
Oxygen
Cobalt
Nickel
Cadmium
Organic solvents
Sulfates
Copper
Permittivity
Solubility
Association reactions
Crystalline materials
Water

Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.",
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AU - Gorbunov, A.O.

AU - Skripkin, M. Yu

AU - Nikol’skii, A.B.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

AB - The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

KW - competing solvation

KW - crystal solvates

KW - d-elements salts

KW - electrolyte solutions

KW - solubility

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