A new family of clusters containing a silver-centered tetracapped [Ag@Ag4(μ3-P)4] tetrahedron, inscribed within a N12 icosahedron

A new family of clusters containing a silver-centered tetracapped [Ag@Ag₄(μ₃-P)₄] tetrahedron, inscribed within a N₁₂ icosahedron

Research output: Contribution to journal › Article › peer-review

DOI

https://doi.org/10.1039/C7DT02597a
Final published version
https://doi.org/10.1039/c7dt02597a
Final published version

Alexander V. Artem'Ev
Irina Yu Bagryanskaya
Evgeniya P. Doronina
Peter M. Tolstoy
Artem L. Gushchin
Mariana I. Rakhmanova
Alexander Yu Ivanov
Anastasiya O. Suturina

An unprecedented silver-centered P-tetracapped [Ag@Ag₄(μ₃-P)₄] tetrahedron inscribed within a N₁₂ icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting Ag^I salts with tris(2-pyridyl)phosphine (Py₃P).

Original language	English
Pages (from-to)	12425-12429
Number of pages	5
Journal	Dalton Transactions
Volume	46
Issue number	37
DOIs	https://doi.org/10.1039/C7DT02597a https://doi.org/10.1039/c7dt02597a
State	Published - 2017

Scopus subject areas

Inorganic Chemistry

ID: 9328493