A new approach to the study of the structure of polyisoprene obtained by cationic polymerization

V. A. Rozentsvet, V. G. Kozlov, O. A. Stotskaya, S. N. Smirnov, P. M. Tolstoy

Research outputpeer-review

Abstract

The use of the T 2 filter in NMR studies allowed us to separate carbon atoms by their mobility in different fragments of the macromolecular chain of polyisoprene synthesized by cationic polymerization. The NMR signals of terminal units with conjugated double bonds were identified for the first time for the “cationic” polyisoprene, which experimentally confirmed the transfer of the growing chain to the monomer in the process of cationic polymerization of isoprene.

Original languageEnglish
Pages (from-to)116-120
Number of pages5
JournalRussian Chemical Bulletin
Volume68
Issue number1
DOIs
Publication statusPublished - 1 Jan 2019

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Polyisoprenes
Cationic polymerization
Nuclear magnetic resonance
Carbon
Monomers
Atoms
isoprene

Scopus subject areas

  • Chemistry(all)

Cite this

Rozentsvet, V. A., Kozlov, V. G., Stotskaya, O. A., Smirnov, S. N., & Tolstoy, P. M. (2019). A new approach to the study of the structure of polyisoprene obtained by cationic polymerization. Russian Chemical Bulletin, 68(1), 116-120. https://doi.org/10.1007/s11172-019-2425-3
Rozentsvet, V. A. ; Kozlov, V. G. ; Stotskaya, O. A. ; Smirnov, S. N. ; Tolstoy, P. M. / A new approach to the study of the structure of polyisoprene obtained by cationic polymerization. In: Russian Chemical Bulletin. 2019 ; Vol. 68, No. 1. pp. 116-120.
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Rozentsvet, VA, Kozlov, VG, Stotskaya, OA, Smirnov, SN & Tolstoy, PM 2019, 'A new approach to the study of the structure of polyisoprene obtained by cationic polymerization', Russian Chemical Bulletin, vol. 68, no. 1, pp. 116-120. https://doi.org/10.1007/s11172-019-2425-3

A new approach to the study of the structure of polyisoprene obtained by cationic polymerization. / Rozentsvet, V. A.; Kozlov, V. G.; Stotskaya, O. A.; Smirnov, S. N.; Tolstoy, P. M.

In: Russian Chemical Bulletin, Vol. 68, No. 1, 01.01.2019, p. 116-120.

Research outputpeer-review

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