2-Chlorobenzoate Complex of Cu(II)

Unexpected Appearance of Halogen center dot center dot center dot Halogen Contacts in Solid State

Sergey A. Adonin, Mikhail D. Petrov, Alexander S. Novikov, Rishat R. Shiriyazdanov, Maxim N. Sokolov, Vladimir P. Fedin

Research outputpeer-review

Abstract

Complex of copper [Cu-2(2-ClBenz)(4)((acetone)(2)] (2-ClBenz=2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via ClCl contacts (3.440 angstrom); their energies were estimated by theoretical methods.

Original languageEnglish
Pages (from-to)857-861
Number of pages5
JournalJournal of Cluster Science
Volume30
Issue number4
DOIs
Publication statusPublished - Jul 2019

Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)
  • Biochemistry

Cite this

Adonin, Sergey A. ; Petrov, Mikhail D. ; Novikov, Alexander S. ; Shiriyazdanov, Rishat R. ; Sokolov, Maxim N. ; Fedin, Vladimir P. / 2-Chlorobenzoate Complex of Cu(II) : Unexpected Appearance of Halogen center dot center dot center dot Halogen Contacts in Solid State. In: Journal of Cluster Science. 2019 ; Vol. 30, No. 4. pp. 857-861.
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abstract = "Complex of copper [Cu-2(2-ClBenz)(4)((acetone)(2)] (2-ClBenz=2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via ClCl contacts (3.440 angstrom); their energies were estimated by theoretical methods.",
keywords = "Carboxylate complexes, Copper, Crystal structure, Halogen bonding, Supramolecular contacts, CARBOXYLATE BRIDGES, S-ALKYL DERIVATIVES, MOLECULAR-STRUCTURE, BINUCLEAR COPPER(II) COMPLEXES, PYRIDINE, X-RAY-STRUCTURE, ACID. CRYSTAL-STRUCTURE, COORDINATION POLYMERS, METAL-IONS, BOND",
author = "Adonin, {Sergey A.} and Petrov, {Mikhail D.} and Novikov, {Alexander S.} and Shiriyazdanov, {Rishat R.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
year = "2019",
month = "7",
doi = "10.1007/s10876-019-01574-z",
language = "English",
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pages = "857--861",
journal = "Journal of Cluster Science",
issn = "1040-7278",
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}

2-Chlorobenzoate Complex of Cu(II) : Unexpected Appearance of Halogen center dot center dot center dot Halogen Contacts in Solid State. / Adonin, Sergey A.; Petrov, Mikhail D.; Novikov, Alexander S.; Shiriyazdanov, Rishat R.; Sokolov, Maxim N.; Fedin, Vladimir P.

In: Journal of Cluster Science, Vol. 30, No. 4, 07.2019, p. 857-861.

Research outputpeer-review

TY - JOUR

T1 - 2-Chlorobenzoate Complex of Cu(II)

T2 - Unexpected Appearance of Halogen center dot center dot center dot Halogen Contacts in Solid State

AU - Adonin, Sergey A.

AU - Petrov, Mikhail D.

AU - Novikov, Alexander S.

AU - Shiriyazdanov, Rishat R.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/7

Y1 - 2019/7

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AB - Complex of copper [Cu-2(2-ClBenz)(4)((acetone)(2)] (2-ClBenz=2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via ClCl contacts (3.440 angstrom); their energies were estimated by theoretical methods.

KW - Carboxylate complexes

KW - Copper

KW - Crystal structure

KW - Halogen bonding

KW - Supramolecular contacts

KW - CARBOXYLATE BRIDGES

KW - S-ALKYL DERIVATIVES

KW - MOLECULAR-STRUCTURE

KW - BINUCLEAR COPPER(II) COMPLEXES

KW - PYRIDINE

KW - X-RAY-STRUCTURE

KW - ACID. CRYSTAL-STRUCTURE

KW - COORDINATION POLYMERS

KW - METAL-IONS

KW - BOND

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