Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation

A.P. Molchanov, M.M. Efremova, M.A. Kryukova, M.A. Kuznetsov

Research outputpeer-review

Abstract

The first example of the cycloaddition of in situ-generated azomethine imine under microwave conditions is described. The reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones proceeds regio- and stereoselectively giving mostly good yields of the corresponding perhydropyrazolopyrazoles. The products of the reaction undergo cycloreversion under the reaction conditions.
Translated title of the contributionСелективное и обратимое 1,3-диполярное циклоприсоединение 6-aryl-1,5-диазабицикло[3.1.0]гексанов к 1,3-дифенилпроп-2-ен-1-онам при микроволновом облучении
Original languageEnglish
Pages (from-to)2679-2686
JournalBeilstein Journal of Organic Chemistry
Volume16
DOIs
Publication statusPublished - 30 Oct 2020

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