Methods for the synthesis of O-, S- and N-vinyl derivatives

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21 Scopus citations

Abstract

The published data on the reactions of alcohols, thiols and various nitrogen-containing compounds with acetylene, resulting in the corresponding vinyl derivatives, are considered. The attention is focused on the application of convenient acetylene sources. Other modern approaches to the synthesis of vinyl derivatives are described in detail, including vinyl exchange and metathesis reactions, various types of cross-coupling and cleavage of organic compounds. Some specific synthetic routes to vinyl ethers, vinyl sulfides and enamines are presented in the last Section.

Translated title of the contributionМетоды синтез O,S,N-винильных производных
Original languageEnglish
Pages (from-to)167-191
Number of pages25
JournalRussian Chemical Reviews
Volume87
Issue number2
DOIs
StatePublished - 2018

Scopus subject areas

  • Chemistry(all)

Keywords

  • ALKALI-METAL HYDROXIDES
  • BETA-PHENYLSELENOETHANOL
  • CALCIUM CARBIDE
  • EFFICIENT REAGENT
  • HIGHLY EFFICIENT
  • NUCLEOPHILIC-ADDITION
  • PHASE INTRAMOLECULAR DEHYDRATION
  • POTASSIUM ALKENYLTRIFLUOROBORATE SALTS
  • RING-OPENING/CROSS-METATHESIS
  • SUPERBASIC CATALYTIC-SYSTEMS

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